Biological Aspects of Electrochemistry: Proceedings of the by H. Berg (auth.), Giulio Milazzo, Peter E. Jones, Liliana

By H. Berg (auth.), Giulio Milazzo, Peter E. Jones, Liliana Rampazzo (eds.)

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Additional info for Biological Aspects of Electrochemistry: Proceedings of the 1st International Symposium. Rome (Italy) Istituto Superiore di Sanit`, May 31st to June 4th 1971

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1963, 2490. D. THEVENOT and G. HAMMOUYA, this volume, p. 631. Streaming Potentials: Theory and Examples In Biological Systems by M. CIGNITTI Istituto Superiore di Sanita, Laboratori di Chimica, Roma Istituto di Fisiologia Umana, I Cattedra, Universita di Roma, Italy Summary The theory of streaming potentials is briefly rewieved. relative to biological systems are discussed. Some examples Streaming potentials 1 Electrokinetic phenomena are defined as those phenomena involving electricity and connected with the movement of two phases along each other.

Tissue Res. 1, 252 (1968). M. CIGNITTI, F. FIGURA, M. MARCHETTI and A. SALLEO, Boll. Soc. Ital. BioI. Spero 45, 273 (1969). E. L. JAHN, Clinical Orthopeadics and Related Research 56, 261 (1968). C. ASHER, Nature 217, 134 (1968). J. M. DIAMOND, J. Membrane BioI. 1, 92 (1969). I. I. A. Summary The relations are summarized between potential, current and derived data, as obtained by polarographically derived technics, and (a) reversibility of electron-transfer processes and the various factors producing irreversibility in such processes, and (b) the study of homogeneous solution kinetics, the kinetics of reactions occurring near the electrode whose equilibria are perturbed by electrolytic processes, and heterogeneous electron-transfer kinetics.

COOH + HOR, (I1Go > 0) CONDENSATIONS THROUGH SIMPLE TRANSFERS: Coupling process = hydrolysis generating one moiety of produced condensate. 1 - Transacylations. ,.. P + HScoA --+ Acyl-ScoA + HaPO. ,.. ,.. 2 - Transphosphorylations. Ex: Trans o. 3 - Transhemiacetalisations. Glucose-UDP 3 - + Glycogen --+ Glu-Glycogen + UDP CONDENSATIONS THROUGH DEHYDRATING REDOX PROCESSES: Coupling process = redox reaction. The name "simple transfer" is well justified by the facts that the moiety R, the dehydration and the necessary energy are transfered from the RA' initial condensate to the RA final one.

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